These are known to be key intermediate products of transport fossil and bio-fuels combustion and are also dangerous pollutants emitted from combustion in internal combustion engines and from gasification of biomasses. In this study, an experimental and kinetic modeling investigation of propanal, n-butanal and n-pentanal pyrolysis and oxidation in two shock tube facilities was carried out. A comprehensive sub-mechanism for the high temperature kinetics of the three aldehydes was developed. The inclusion of the aldehydes sub-mechanism in two different kinetic environments, required modifications for the H-abstraction reactions, due to different rate rules in use in the two kinetic environments, and due to differences in the C0 C4 kinetic schemes. Both of the models were validated and showed good agreement with the new experimental data. The mechanisms are also satisfactorily compared with ignition delay times, speciation profiles and laminar burning velocities previously published in literature. Reaction pathways and sensitivity analyses were also performed to highlight the important reaction steps involved in the pyrolysis and oxidation processes. The major differences between the models and the experiments have to be attributed to the chemistry of the smaller species, more than to aldehyde specific reactions.
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Jenna Nannetti and Mike Simons. This story contains exclusive video and audio clips of the defendants’ police confessions. Due to poor sound quality, viewers may need to turn computer speakers to maximum volume. Mike Simons and Jenna Nannetti sat on the porch and made out. It was a Sunday night last October in the quiet suburban community of Livermore, some thirty miles east of Oakland. From the way the two of them were grooving on each other, it looked like things just might work out.
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You’ll find an array of antique and specialty shops plus fine dining nestled within the scenic atmosphere of historic buildings and natural beauty. The Village of Arroyo Grande is well known for its annual Festivals and weekly Farmer’s Market that are enjoyed by thousands of visitors and local residents. Join us in celebration of the local harvest and major holidays when the Village of Arroyo Grande abounds with a variety of arts and crafts, tempting treats, and fun activities.
Rich in History, Rich in Fun The Village is filled with historic buildings from the late ‘s – early ‘s and has the the last “swinging bridge” of its kind in California. Five museums and a historic reference library recreate the history of the area with artifacts dating back to the days of the early settlers. We invite you to stroll the streets of the Village and discover the wonderful shops and restaurants that are available.
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Carbon is abundant in the Sun , stars , comets , and in the atmospheres of most planets. PAHs seem to have been formed “a couple of billion years” after the Big Bang , are widespread throughout the universe, and are associated with new stars and exoplanets. This is much more than the amount of carbon in the oceans or atmosphere below. Hydrocarbons such as coal , petroleum , and natural gas contain carbon as well.
Various estimates put this carbon between , Gt ,  or 3, Gt. According to one source, in the period from to about gigatonnes of carbon were released as carbon dioxide to the atmosphere from burning of fossil fuels. Natural diamonds occur in the rock kimberlite , found in ancient volcanic “necks”, or “pipes”. Diamonds are now also being recovered from the ocean floor off the Cape of Good Hope.
These asteroids have not yet been directly sampled by scientists. The asteroids can be used in hypothetical space-based carbon mining , which may be possible in the future, but is currently technologically impossible. Isotopes of carbon Isotopes of carbon are atomic nuclei that contain six protons plus a number of neutrons varying from 2 to
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The inset shows a closeup of a sample holder. The precise measurement capabilities at CAMS allow researchers to identify the isotopic composition of a given sample. One important research endeavor involves determining the precise age of biological material generated in the past 60 years by measuring the ratio of radiocarbon or carbon to the carbon and carbon in samples.
Scientific forensics using radiocarbon bomb-pulse dating is possible because of the isotopic signature created by aboveground nuclear testing between and , which nearly doubled the amount of carbon in the atmosphere. When the aboveground test-ban treaty took effect in , atmospheric levels of radiocarbon began to decline as carbon migrated into the oceans and biosphere.
Living organisms naturally incorporate carbon into their tissues as the element moves through the food chain. As a result, the concentration of carbon leaves an indelible time stamp on every biological molecule when it comes into being. To extract carbon for measurement, researchers at CAMS turn a sample into carbon dioxide through either combustion or a chemical process and then reduce the carbon dioxide to graphite—a form of carbon—on an iron catalyst.
See the box below. From the beginning, CAMS has been about collaboration, bringing excellent people and excellent science together in an environment that encourages teamwork. The Multi-User Tandem Laboratory initially focused on using accelerator mass spectrometry AMS to diagnose fission products of atomic tests and to conduct research in materials science, nuclear astrophysics, nuclear spectrometry, and neutron physics. Academic collaboration was encouraged from the very first, and in , Lawrence Livermore established the Center for Accelerator Mass Spectrometry to coordinate the increasing number of experiments with academic users.
The center operates around the clock, performing up to 25, measurements per year. The research made possible by CAMS covers areas as diverse as archaeology, atmospheric chemistry, biomedicine, carbon-cycle dynamics, earth system processes, cell biology, alternative fuels, forensic dating, and forensic reconstruction of radiation doses.
Lipodystrophy Administration of insulin subcutaneously, including Lantus, has resulted in lipoatrophy depression in the skin or lipohypertrophy enlargement or thickening of tissue in some patients [see Dosage and Administration 2. Insulin initiation and intensification of glucose control Intensification or rapid improvement in glucose control has been associated with a transitory, reversible ophthalmologic refraction disorder, worsening of diabetic retinopathy, and acute painful peripheral neuropathy.
However, long-term glycemic control decreases the risk of diabetic retinopathy and neuropathy. Weight gain Weight gain has occurred with some insulin therapies including Lantus and has been attributed to the anabolic effects of insulin and the decrease in glucosuria.
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It has some wineries, seventeen manicured golf courses, a county fair with enchanting echoes of America’s rural past. Pleasanton is a close knit community graced by heritage oaks and restored vintage buildings dating back to the ‘s. Cutting-edge cuisine and one-of-a-kind shops with contemporary flair. The Tri-Valley includes four cities, one town and three converging valleys.
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The summit of Mount Diablo Mount Diablo is sacred to many California Native American peoples; according to Miwok mythology and Ohlone mythology , it was the point of creation. Prior to European entry, the creation narrative varied among surrounding local groups. In one surviving narrative fragment, Mount Diablo and Reed’s Peak Mount Tamalpais were surrounded by water; from these two islands the creator Coyote and his assistant Eagle-man made Native American people and the world.
Their members spoke dialects of three distinct languages:
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German Renner Action Parts The images above can be enlarged by clicking on them The reasons we choose this maker is a track record of proven quality since , and exact geometry reproduction for vintage Steinway and Sons pianos. Renner produces more than 3 different shank and flange configurations, and 3 different wippen configurations. These choices provide the exact fitment needed to make a vintage Steinway perform and feel perfect. The quality of the Renner hardwood Hornbeam used on the parts exceeds the specifications of maple, and the center-pinning is always firm and sluggish-free.
The premium blue Renner hammers produced are offered in many different sizes and weights that can exactly duplicate what was originally intended for use in the vintage Steinway action. The Renner hammer uses Wurzen wool felt which is considered the premium material to make a hot pressed hammer. Renner action parts are currently used by the finest piano makers in the world which include: Nothing we have used in the past comes close to the quality of Renner parts. Genuine American Steinway factory action parts The images above can be enlarged by clicking on them Simply stated, the American Steinway factory replacement parts have undergone a tremendous improvement in quality over the last few years.
Steinway currently offers 2 different American shank and flange configurations standard round maple shanks, and a new hexagonal maple shank , and their standard wippen replacement.
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A 4, unit housing project was completed in Richmond during The Ohlone were the first inhabitants of the Richmond area, settling an estimated 5, years ago. Edmund Randolph, originally from Richmond, Virginia , represented the city of San Francisco when California’s first legislature met in San Jose in December , and he became state assemblyman from San Francisco. His loyalty to the town of his birth caused him to persuade a federal surveying party mapping the San Francisco Bay to place the names"Point Richmond” and"Richmond” on an geodetic coast map, which was the geodetic map at the terminal selected by the San Francisco and San Joaquin Valley Railroad ; and by maps made by the railroad carried the name"Point Richmond Avenue”, designating a county road that later became Barrett Avenue, a central street in Richmond.
Until the enactment of prohibition in , the city had the largest winery in the world;  the small abandoned village of Winehaven remains fenced off along Western Drive in the Point Molate Area. Starting in , and continuing through the s, the Ku Klux Klan was active in the city. The old Ford plant has been a National Historic Place since , and in was purchased by developer Eddie Orton  aas been converted into an events center Ford Point Building — The Craneway.
Standard Oil set up operations here in , including what is now the Chevron Richmond Refinery and tank farm , which are still operated by Chevron. Greely built in Richmond At the outset of World War II, the four Richmond Shipyards were built along the Richmond waterfront, employing thousands of workers, many recruited from all over the United States, including many African-Americans and women entering the workforce for the first time.
Many of these workers lived in specially constructed houses scattered throughout the San Francisco Bay Area, including Richmond, Berkeley and Albany. A specially built rail line, the Shipyard Railway , transported workers to the shipyards.